But group-2 carbonates are soluble in a solution of CO 2 due to formation of HCO 3-. charge density), there is significant difference in terms of their ability to hydrate. 000+ LIKES. Apart from being the largest NEET community, EduRev has the largest solved It also identifies and explains the trend in the solubility and thermal stability of group 2 metal compounds. 100+ LIKES. The solubility of the Group 2 sulphates decreases down the group. Magnesium sulphate dissolves in water whereas barium sulphate does not. a) Virtually no reaction occurs between magnesium and cold water. | EduRev NEET Question is disucussed on EduRev Study Group … The effect of heat on the Group 2 nitrates. BeSO 4 Fairly soluble. (c)Sulphate-thermal stability is good for both alkali and alkaline earth metals. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. The relative decomposition temperatures are: MnSO 4 755, FeSO 4 537, CoSO 4 708, NiSO 4 675, CuSO 4 598, ZnSO 4 646, CdSO 4 816, PbSO 4 803, MgSO 4 895, CaSO 4 1149, and SrSO 4 1374°C. Top Be. Thermal decomposition is the term given to splitting up a compound by heating it. As you go down the Group, the carbonates have to be heated more strongly before they will decompose. In group 1 and 2, the nitrates and carbonates get more stable down the group. Start studying Solubility of Group 2 Hydroxides and Sulphates. Learn vocabulary, terms, and more with flashcards, games, and other study tools. By continuing, I agree that I am at least 13 years old and have read and Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO 3(s) CaO(s) + CO 2(g) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. This means that beryllium carbonate decomposes at a lower temperature to the rest of the group. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. 2.0k SHARES. Alkali Earth Metals Group 1. The Questions and Due to the large size of the sulphate anion there is little difference between the lattice energies for these compounds. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. All group II elements react in air to form an oxide layer. This is clearly seen if we observe the reactions of magnesium and calcium in water. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. Solubility. As you go down the group, the energy needed to break up the lattice falls as the positive ions get bigger. The sulphates of alkaline earth metals are all white solids. This is clearly seen if we observe the reactions of magnesium and calcium in water. SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The relative decomposition temperatures are: MnSO4 755, FeSO4 537, CoSO4 708, NiSO4 675, CuSO4 598, ZnSO4 646, CdSO4 816, PbSO4 803, MgSO4 895, CaSO4 1149, and SrSO4 1374°C. 3.2k SHARES. over here on EduRev! Mg(s) + H2O(g) → MgO(s) + H2(g) b) Calcium is more reactive. The solubility of carbonates increases down the group in alkali metals (except ) . But carbonates of alkaline earth metals are insoluble in water. As the size of the Group 2 cations increases down the group, the difference between the size of the metal cations and the size of the SO 4 2-ions decreases. Arrange the following sulphates of alkaline earth metals in order of decreasing thermal stability: . If you add sodium sulphate or sulphuric acid to an aqueous solution containing calcium, strontium or barium ions a white precipitate forms:. However, in a reaction with steam it forms magnesium oxide and hydrogen. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO3(s ) CaO(s) + CO2(g ) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. As we move down the group 2 the size of cations increases and sulphate is a big ion group according to its size. The term "thermal decomposition" describes splitting up a compound by heating it. Solubility: The solubility of the sulphates in water decreases down the groups i.e. This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. This is affected by the radius of the cation, which is more able to polarise the anion when the cation is small and highly charged. Ca(s) + H2O(l) → Ca(OH)2(aq) + H2(g) The sulphate of alkaline earth metals is less soluble. More the strong bonding more thermal stability. In this video we want to explain the trends that we observe for thermal decomposition temperatures for Group 2 Metal Salts. solubility: sulphates of alkali metals are soluble in water. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. Sulphates of both group 1 and group 2 metals are stable towards heat. For Alkaline Earth metals Group 2. M (OH) 2 + H 2 SO 4 → MSO 4 + 2H 2 O MCO 3 + H 2 SO 4 → MSO 4 + CO 2 + H 2 O . Nitrates of group -1 and group-2 metals are all soluble in water. soon. Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. The solubilities of these salts further increase on descending the group. Factors possibly influencing thermal stability of … The effect of heat on the Group 2 carbonates. Reactivity increases down the group. Question bank for NEET. Thermal stability is a chemical process whereby the components of the lattice react causing decomposion to more stable products. Solubility of Carbonates and Sulphates DECREASES from top to bottom. Less attractions are formed with water molecules. 3.2k VIEWS. Reactivity of Group II elements increases down the group. BaSO 4 (s) (thick white precipitate forms); Sr 2+ + SO 4 2-(aq) ? This discussion on How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? Again the reactivity increases down the group, all forming a white oxide. Beryllium carbonate decomposing most easily. are solved by group of students and teacher of NEET, which is also the largest student This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements – beryllium, magnesium, calcium, strontium and barium. Properties of Sulphates of Alkali Earth Metals. Hence polarising ability of the M2+ ion decreases down the group. Solubility of Carbonates INCREASES(opposite of group 2) from top to bottom. The larger the anion the easier the distortion, as seen with the carbonate ion. Reactivity increases down the group. The thermal stability of alkaline earth metals increases down the group for hydroxides i-e., Be(OH)2 is less stable than Ba(OH)2. The higher the temperature needed to decompose something, the more thermally stable it is. The greater the charge density the easier it is for the cation to hydrate and hence dissolve in water due to greater attraction with the polar water molecules. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. Arrange sulphates of group in decreasing order of solubility of water. Answers of How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? community of NEET. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. It reacts with cold water to produce an alkaline solution of calcium hydroxide and hydrogen gas is released. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Group II elements are less reactive than the corresponding Group I element in the same period, since two rather than one electron need to be lost in order to gain noble gas configuration. However, sulphates of alkaline earth metals show varied trends. It however shows reversible decomposition in closed container c i e n o t e s . agree to the. The carbonates become more stable to heat as you go down the Group. a) Virtually no reaction occurs between magnesium and cold water. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. All these carbonates decompose on heating to give CO 2 and metal oxide. Thermal decomposition of Group 2 nitrates has a similar pattern, decompose to form nitrogen dioxide, oxygen and the oxide: Order of stability: 6 | P a g e h t t p s : / / w w w . is done on EduRev Study Group by NEET Students. This can be explained by the increase in ease at losing two outer electrons as we descend the group. Thermal stability is the decomposition of compounds on heating. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Bottom Ba. The thermal stability of Group II carbonates increases as we descend the group. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? All the Group 2 carbonates and their resulting oxides exist as white solids. All of the Group 2 sulphates consist of 2+ ions attracting 2- ions, and so the only thing that matters is the distance between the ion centres. All the enthalpy definitions including Lattice Enthalpy, Enthalpy of Hydration and Enthalpy of solutions. The increasing thermal stability of Group 2 metal salts is consistently seen. Solubility of Hydroxides and Flourides INCREASES from top to bottom. If the answer is not available please wait for a while and a community member will probably answer this Be > Mg > Ca > Sr > Ba. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. Alkali metal sulphates are more soluble in water than alkaline earth metals. Sulphates of alkali metals are soluble in water. Charge Density and Polarising Power of Group 2 Metal Cations. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. The resource is set out as teachers' notes followed by the students' page which presents the task to be investigated. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than The greater the distortion caused by the polarising ion the less stable the compound is to heat. Li to Na. However, in a reaction with steam it forms magnesium oxide and hydrogen. 1. Ionisation energy decreases due to extra shielding from inner shells and increase in distance from the nucleus. You can study other questions, MCQs, videos and tests for NEET on EduRev and even discuss your questions like The loss of electrons becomes easier due to the decreasing ionisation energy required. The thermal stability increases down the group for sulphates of alkaline earth metals. The solubility of these sulphates decreases as we descend the group, with barium sulphate being insoluble in water. Thermal Stability is the decomposition of a compound on heating. Even for hydroxides we have the same observations. EduRev is a knowledge-sharing community that depends on everyone being able to pitch in when they know something. The reason, once more, is that the polarising power of the M2+ decreases as ionic radius increases. 2.0k VIEWS. Whereas bicarbonates give carbonate, water and carbon dioxide. b) Calcium is more reactive. MgSO 4 Soluble. So what causes this trend? Thermal stability of sulphates of alkaline earth metals increases down the group Ask for details ; Follow Report by Priya4334 22.01.2019 hmmm D.A.V Ba 2+ + SO 4 2-(aq) ? Let's use MgCO 3 as an example. and big group of compounds are stable with big ionic group. The size of the sulphate ion is larger compared to the Group 2 cations. MgCO3(s ) MgO(s) + CO2(g ) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product However, due to the change in ionic radius (i.e. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. Alkaline Earth Metals (Group II Elements), Chemical Properties of Alkaline Earth Metals, Transistor Biasing Circuits and Thermal Stability, Group 2 Elements: Alkaline Earth Metals-General Properties. Thanks for viewing. All of these carbonates are white solids, and the oxides that are produced are also white solids. Thermal stability. Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? The larger compounds further down require more heat than the lighter compounds in order to decompose. FAQs on Appendix - … To help you revise your definitions and equations. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. … SrSO 4 (s) (thick white precipitate forms); Ca 2+ + SO 4 2-(aq) ? The thermal stability of the nitrates follows the same trend as that of the carbonates, with thermal stability increasing with proton number. Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. All the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. Be heated more strongly before they will decompose EduRev study group by NEET students ion... And big group of students and teacher of NEET oxide layer their resulting exist. It reacts with cold water give carbonate, water and carbon dioxide gas hence polarising ability of the sulphate there. Be explained by the students ' page which presents the task to heated. 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